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4CH1

Elements, Compounds and Mixtures

Principles of Chemistry · 2 question types

Practise
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4CH1 Topics

States of Matter6%
Elements, Compounds and Mixtures5%
  1. Element, Compound or Mixture
  2. Pure Substances and Mixtures
  3. Separation Techniques
  4. Interpreting Chromatograms
  5. Practical: Paper Chromatography of Food Colourings
Atomic Structure9%
The Periodic Table8%
Chemical Formulae, Equations and Calculations17%
Ionic Bonding9%
Covalent Bonding8%
Metallic Bonding5%
Electrolysis7%

Frequency legend

High (≥14%)
Above avg (10 to 13%)
Average (<10%)

Exam Frequency Analysis

Past paper frequency (2018 to 2024)

This topic accounts for approximately 5% of your exam marks.

stable
Rare
Stable5%

Definitions and separation techniques tested consistently across both papers.

  • Every chemical substance falls into one of three classes:
    • Element
    • Compound
    • Mixture
  • Edexcel expects you to classify a substance from its name, formula, or particle diagram

Element

  • Built entirely from atoms that all share the same proton number
  • Each element has its own characteristic proton number (e.g. gold = 79, oxygen = 8)
  • Cannot be reduced to anything simpler by ordinary chemical or physical methods
  • 118 elements are known, all set out in the Periodic Table
  • Examples: iron (Fe), copper (Cu), magnesium (Mg), oxygen (O₂), nitrogen (N₂), sulfur (S₈)
  • Diatomic and polyatomic forms are still elements
    • O₂ is an element (not a compound), because every atom in it is oxygen

Compound

  • A pure substance formed when atoms of two or more different elements join in a fixed ratio through chemical bonds
  • Has its own chemical properties, different from those of its elements
  • Can only be broken back into its elements by another chemical reaction (not by physical means)
  • Millions of different compounds exist
  • Composition by mass is fixed
    • Water is always H₂O, never H₃O or H₂O₂
    • Sodium chloride is always one Na per one Cl
  • Examples: water (H₂O), carbon dioxide (CO₂), calcium carbonate (CaCO₃), copper(II) sulfate (CuSO₄)

Mixture

  • Two or more substances (any combination of elements and compounds) sharing the same space, with no chemical bonds between them
  • Each component keeps its own chemical identity and properties
  • Proportions can vary (a salt solution can be weak or strong)
  • Components can be separated again by physical methods
  • Examples:
    • Air (mostly N₂ and O₂, plus Ar, CO₂, water vapour)
    • Seawater (water + dissolved salts)
    • Iron filings + sulfur powder
    • Brass (copper + zinc)

Recognising the class from a formula

What you seeClassExamples
One element symbol only (optionally with subscript denoting a molecule of that element)ElementCu, O₂, S₈, P₄
Two or more different element symbols bonded as one unitCompoundH₂O, NaCl, CaCO₃, NH₃
Two or more formulae written separately ("+", "and", or in a list)MixtureFe + S; sand + water; air

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Practical: Measuring the Solubility of a Solid at a Fixed Temperature

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Pure Substances and Mixtures