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4CH1

Chemical Tests

Inorganic Chemistry · 4 question types

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4CH1 Topics

Group 1: The Alkali Metals5%
Group 7: The Halogens6%
Gases in the Atmosphere5%
The Reactivity Series6%
Extraction and Uses of Metals6%
Acids, Alkalis and Titrations10%
Acids, Bases and Salt Preparations8%
Chemical Tests8%
  1. Tests for Gases
  2. Flame Tests for Metal Cations
  3. Tests for Cations with Sodium Hydroxide
  4. Tests for Anions
  5. Tests for Water

Frequency legend

High (≥14%)
Above avg (10 to 13%)
Average (<10%)

Exam Frequency Analysis

Past paper frequency (2018 to 2024)

This topic accounts for approximately 8% of your exam marks.

stable
Low
Stable8%

Ion tests, flame tests and gas tests all appear regularly; expect to recall observations.

Why these five gases matter

  • Many cation, anion and water tests release a gas that then has to be identified
  • You are expected to recognise the test, the positive result, and the name of the gas in each case
  • The five gases assessed are ammonia, carbon dioxide, chlorine, hydrogen and oxygen
GasTestPositive result
Ammonia, NH3Hold a piece of damp red litmus paper at the mouth of the tubeThe paper turns blue
Carbon dioxide, CO2Bubble the gas through limewater (Ca(OH)2(aq))The limewater turns milky (cloudy white)
Chlorine, Cl2Hold a piece of damp blue litmus paper at the mouth of the tubeThe paper turns red and is then bleached white
Hydrogen, H2Hold a lit splint at the mouth of the tubeA loud squeaky pop sound (hydrogen burns rapidly with the oxygen in the air)
Oxygen, O2Hold a glowing splint inside the mouth of the tubeThe splint relights

Things to be careful about

  • For ammonia: keep the litmus paper just at the mouth of the tube and clear of the inner walls, so any alkali residue on the glass does not give a false positive
  • For carbon dioxide: a burning splint does go out in CO2, but it also goes out in nitrogen and many other gases, so the splint test is not a valid identification — only the limewater test is accepted
  • For chlorine: the paper goes red first because chlorine reacts with the moisture to form an acid, then bleaches as the chlorine attacks the dye; do the test in a fume cupboard because chlorine is toxic
  • For hydrogen vs oxygen: a ligHted splint identifies Hydrogen; a glOwing splint identifies Oxygen — the H and O hidden inside each word avoid the common mix-up
  • For oxygen: a "much brighter glow" usually counts as a positive result, but in an exam stick to the textbook answer "relights the glowing splint"
Exam tip

Testing for chlorine gas

What comes up: Describe the test and the positive result for chlorine.

Write (two marks): (1) Hold a piece of damp blue litmus paper at the mouth of the tube. (2) The paper first turns red, then is bleached white.

Watch out: Chlorine dissolves in the moisture on the paper to form an acidic solution, so damp blue litmus turns red before the chlorine bleaches it white. If you start with red litmus paper the red-to-red colour change is not visible, so only the bleaching (turning white) shows. The mark scheme credits only one mark if you use red litmus paper (the bleaching step only). To score both marks you must specify damp blue litmus paper and state it turns red then is bleached white, or simply state it is bleached/turns white.

Exam tip

Hydrogen vs oxygen — lighted splint or glowing splint?

What comes up: State the test and the positive result for hydrogen or oxygen.

Write: For hydrogen, hold a lighted (lit) splint at the mouth of the tube — you hear a squeaky pop. For oxygen, insert a glowing splint into the tube — the splint relights.

Watch out: The mark scheme explicitly rejects using a glowing splint to test for hydrogen. A lighted splint for the oxygen test will also not score full marks. Keep the two separate: lighted = hydrogen, glowing = oxygen.