Physical Chemistry · 3 question types
Past paper frequency (2018 to 2024)
This topic accounts for approximately 7% of your exam marks.
Calorimetry calculations and energy profile diagrams appear in nearly every series.
| Diagram | Reactant level vs product level | Arrow direction | Sign of ΔH |
|---|---|---|---|
| Exothermic | Reactants higher than products | Arrow points down | ΔH negative |
| Endothermic | Reactants lower than products | Arrow points up | ΔH positive |
Drawing and labelling an energy level diagram
What comes up: draw or complete a reaction profile for an exothermic or endothermic reaction, with correct labels.
Write (four marks): (1) draw a horizontal line for the reactants and a second horizontal line for the products, with the products line at a lower level than the reactants for an exothermic reaction (or higher for endothermic); (2) label each line with the correct formula or name; (3) draw a vertical arrow between the two levels, pointing downward for exothermic, and label it ΔH; (4) draw a curved hump rising from the reactants level and add a vertical arrow from the reactants level up to the peak of the hump, labelled activation energy or Ea.
Watch out: the ΔH arrow must point from the reactants level to the products level — an arrow pointing the wrong way (from products up to reactants, or from the peak down to reactants) is rejected. The mark scheme also rejects an Ea arrow that points downward from the hump to the reactants line.